Short Naphthalene Organophosphonate Linkers to Microporous Frameworks

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Bulut A., ZORLU Y., Worle M., Cetinkaya A., KURT H., Tam B., ...More

CHEMISTRYSELECT, vol.2, no.24, pp.7050-7053, 2017 (Peer-Reviewed Journal) identifier

  • Publication Type: Article / Article
  • Volume: 2 Issue: 24
  • Publication Date: 2017
  • Doi Number: 10.1002/slct.201701411
  • Journal Name: CHEMISTRYSELECT
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.7050-7053

Abstract

We report two novel 3D porous metal-organophosphonate metal organic frameworks (MOFs) [{Cu(4,4'-bpy)(0.5)(1,4-NDPA-H-2)] (1), [{Cu-2(4,4'-bpy)(0.5)}(1,4-NDPA)] (2) and a non-porous [{Cu(4,4'-bpy)}(2,6-NDPA-H-2)] (3) constructed using the structurally rigid 1,4-naphthalenediphosphonic acid (1,4-NDPA-H-4) and 2,6-naphthalenediphosphonic acid (2,6-NDPA-H-4). 1 and 2 exhibit high surface areas obtained using the structurally rigid and short aromatic organophosphonate linkers with copper. The compound 1 has been further analyzed by TGA and Quantum Design PPMS vibrating sample magnetometer.